You seem to believe that you need to open the connection in WinSCP to open PuTTY from WinSCP. You do not have to. You can open the session in PuTTY straight from the WinSCP Login dialog.
Use Manage > Open in PuTTY:
https://winscp.net/eng/docs/ui_login#opening_in_putty
Or even easier, use Login > Open in PuTTY or
Use Manage > Open in PuTTY:
https://winscp.net/eng/docs/ui_login#opening_in_putty
Or even easier, use Login > Open in PuTTY or
Ctrl+P
.